Publications

(39) "Enantioselective Intermolecular Radical Amidation and Amination of Benzylic C-H Bonds via Dual Copper and Photocatalysis"
Chen, X.; Lian Z.*, Kramer, S.*
Angew. Chem. Int. Ed. 2023, 62, e202217638.

Most accessed publication in Angewandte Chemie during February 2023
Highlighted by T. West in Nature Synthesis
Highlighted in Org. Process Res. Dev.

(38) "Carbonylative Cross-Electrophile Coupling between Aryl Bromides and Aryl Triflates Enabled by Palladium and Rhodium Cooperative Catalysis and CO as Reductant"
Chen, G.; Zhou, R.; Zhang, X.; Xiao, X.; Kramer, S.*; Cheng, G.-J.*; Lian, Z.*
ACS Catal. 2022, 12, 14582–14591.

(37) "Photo-induced metal-free dehydrogenative N-N homo-coupling"
Balakrishna, B.; Mossin, S.; Kramer, S.*
Chem. Commun. 2022, 58, 10977–10980.

(36) "Enantioselective Four-Component Arylsulfonylcyanation of Vinylarenes via the Insertion of SO2 enabled by SOgen as SO2 Surrogate"
Chen, L.; Zhang, X.; Zhou, M.; Kramer, S.*, Lian, Z.*
ACS Catal. 2022, 12, 10764–10770.

(35) "Redox-Neutral Ni-Catalyzed sp3 C–H Alkylation of alpha-Olefins with Unactivated Alkyl Bromides"
Buendia, M. B.; Higginson, B.; Kegnæs, S.; Kramer, S.*, Martin, R.*
ACS Catal. 2022, 12, 3815–3820.

(34) “Copper-Catalyzed Alkynylation of Benzylic C–H Bonds with Alkynylboronic Esters”
Buendia, M. B.; Balin, J.-G. J.; Andersen, M. E.; Lian, Z.; Kramer, S.*
Synlett 2022, 33, 150–154.
- Invited contribution in connection with nomination for EuChemS Young Investigator Award

(33) "Design and Applications of a SO2 Surrogate in Palladium-Catalyzed Direct Aminosulfonylation between Aryl Iodides and Amines"
Jia, X.; Kramer, S.; Skrydstrup, T.; Lian, Z.*
Angew. Chem. Int. Ed. 2021, 60, 7353–7359.
- Hot paper

(32) “Heterogeneous Formic Acid Production by Hydrogenation of CO Catalyzed by Ir-bpy Embedded in Polyphenylene Porous Organic
Polymers“
Bennedsen, N. R.; Christensen, D. B.; Mortensen, R. L.; Wang, B.; Kramer, S.*; Kegnæs, S.*
ChemCatChem 2021, 13, 1781–1786.

(31) “Nickel-Catalyzed Cross-Electrophile Coupling Reaction for the Synthesis of gem-Difluorovinyl Arenes”
Xiong, B.; Wang, T.; Sun, H.; Li, Y.; Kramer, S.*; Cheng, G.-J.*; Lian, Z.*
ACS Catal. 2020, 10, 13616–13623.

(30) “A Nickel-Bisdiamine Porous Organic Polymer as Heterogeneous Chiral Catalyst for Asymmetric Michael Addition to Aliphatic Nitroalkenes”
Buendia, M. B.; Kegnæs, S.*; Kramer, S.*
Adv. Synth. Catal. 2020, 362, 5506–5512.

(29) “Dual Nickel/Palladium-Catalyzed Reductive Cross-Coupling Reactions Between Two Phenol Derivatives”
Xiong, B.; Li, Y.; Wei, Y.; Kramer, S.*; Lian, Z.*
Org. Lett. 2020, 22, 6334–6338.

(28) “A Chiral Porous Organic Polymer as Heterogeneous Ligand for Enantioselective Pd-Catalyzed C(sp3)–H Functionalization”
Bennedsen, N. R.; Kramer, S.*; Kegnæs, S.*
Catal. Sci. Technol. 2020, 10, 7697–7705.

(27) “Silylcarboxylic Acid as Bifunctional Reagents: Application in Palladium-Catalyzed External-CO-Free Carbonylative Cross-Coupling Reactions”
Li, X.; Xu, J.; Zhang, X.; Kramer, S.; Skrydstrup, T.; Lian Z.*
Adv. Synth. Catal. 2020, 362, 4078–4083.

(26) “Homogeneous Gold-Catalyzed Aryl-Aryl Coupling Reactions”
Kramer, S.*
Synthesis 2020, 52, 2017–2030.
- Invited contribution

(25) "Nickel-Catalyzed Intramolecular Desulfitative C-N Coupling: A Synthesis of Aromatic Amines"
Liu, J.; Jia, X.; Chen, X.; Sun, H.; Li, Y.; Kramer, S.; Lian, Z.*
J. Org. Chem. 2020, 85, 5702–5711.

(24) "Study of CoCu Alloy Nanoparticles Supported on MOF-Derived Carbon for Hydrosilylation of Ketones"
Christensen, D. B.; Mortensen, R. L.; Kramer, S.; Kegnæs, S.*
Catal. Lett. 2020, 150, 1537–1545.

(23) “Enantioselective Aryl-Aryl Coupling Facilitated by Chiral Binuclear Gold Complexes”
Himmelstrup, J.; Buendia, M. B.; Sun, X.-W.; Kramer, S.*
Chem. Commun. 2019, 55, 12988–12991.

(22) “Palladium on Carbon-Catalyzed α-Alkylation of Ketones with Alcohols as Electrophiles: Scope and Mechanism”
Bennedsen, N. R.; Mortensen, R. M.; Kramer, S.*; Kegnæs, S.*
J. Catal. 2019, 371, 153–160.

(21) "Synthesis of α-Substituted Primary Benzylamines through Copper-Catalyzed Cross-Dehydrogenative Coupling”
Kramer, S.*
Org. Lett. 2019, 21, 65–69.

(20) "Asymmetric Synthesis of Chiral Spiroketal Bisphosphine Ligands and Their Application in Enantioselective Olefin Hydrogenation"
        Huang, J.; Hong, M.; Wang, C.-C.; Kramer, S.*; Lin, G.-Q.; Sun, X.-W.*
        J. Org. Chem. 2018, 83, 12838–12846.
   (Highlighted in SYNFACTS 2018, 14, 1282)

(19) "Porous Organic Polymers Containing Active Mononuclear Metal Centers as Catalysts for Synthetic Organic Chemistry"
Kramer, S.*; Bennedsen, N. R.; Kegnæs, S.*
ACS Catal. 2018, 8, 6961–6982.

(18) "Asymmetric Organocatalytic [4 + 1] Annulations: Enantioselective Construction of Multifunctionalized Spirocyclopentane Oxindoles
        Bearing α,α-Disubstituted α-Amino-β-keto Esters"
        Wang, C.-C.; Huang, J.; Li, X.-H.; Kramer, S.; Lin, G.-Q.; Sun, X.-W.*
        Org. Lett. 2018, 20, 2888–2891.

(17) “Silylative Pinacol Coupling Catalyzed by Nitrogen-Doped Carbon-Encapsulated Nickel/Cobalt Nanoparticles: Evidence for a Silyl Radical
       Pathway”
       Kramer, S.; Hejjo, F.; Rasmussen, K. H.; Kegnæs, S.*
       ACS Catal. 2018, 8, 754–759.

(16) "Cobalt-Nickel Alloy Catalysts for Hydrosilylation of Ketones Synthesized by Utilizing Metal-Organic Framework as Template"
Bennedsen, N. R.; Kramer, S.; Mielby, J. J.; Kegnæs, S.*
Catal. Sci. Technol. 2018, 8, 2434–2440.

(15) “Asymmetric Total Syntheses of (−)-α-Lycorane, (−)-Zephyranthine and Formal Synthesis of (+)-Clivonine”
Chen, Y.-J.; Cai, S.-L.; Wang, C.-C.; Cheng, J.-D.; Kramer, S.; Sun, X.-W.*
Chem. Asian J. 2017, 12, 1309–1313.

(14) “Evidence for Single Electron Pathways in the Reaction Between Palladium(II) Dialkyl Complexes and Alkyl Bromides under Thermal and
       Photo-Induced Conditions”
       Andersen, T. L.; Kramer, S.*; Overgaard, J.; Skrydstrup, T.*
       Organometallics 2017, 36, 2058–2066.

(13) “Nitrogen-Doped Carbon Encapsulated Nickel/Cobalt Nanoparticle Catalysts for Olefin Migration of Allylarenes”
Kramer, S.; Mielby, J. J.; Buss, K. S.; Kasama, T.; Kegnæs, S.*
ChemCatChem 2017, 9, 2930–2934.

(12) “Recent Advances in Gold-Catalyzed Intermolecular Aryl C–H Functionalization”
Kramer, S.*
Chem. Eur. J. 2016, 22, 15584–15598.

(11) “Use of a New Spirophosphine to Achieve Catalytic Enantioselective [4+1] Annulations of Amines with Allenes to Generate
      Dihydropyrroles”
       Kramer, S.; Fu, G. C.*
       J. Am. Chem. Soc. 2015, 137, 3803–3806.

(10) “Access to Dihydroisoquinolines via Gold-Catalyzed Formal [4+2] Cycloaddition”
Xin, Z.; Kramer, S.*; Overgaard, J.; Skrydstrup, T.*
Chem. Eur. J. 2014, 20, 7926–7930.

(9) Kramer, S.; Gagosz, F.
“From Gold in Nature to Gold Catalysts” in Gold Catalysis – An Homogeneous Approach
Toste, F. D.; Michelet, V., Eds.; Imperial College Press, 2014; pp 1–49.

(8) “Divergent Product Selectivity in Gold- versus Silver-Catalyzed Reaction of 2-Propynyloxy-6-Fluoropyridines with Arylamines”
Gronnier, C.; Bel, P. F. D.; Henrion, G.; Kramer, S.; Gagosz, F.*
Org. Lett. 2014, 16, 2092–2095.

(7) “Generation of Stoichiometric Ethylene and Isotopic Derivatives and Application in Transition Metal-Catalyzed Vinylation and Enyne
      Metathesis”
      Min, G. K.; Bjerglund, K.; Kramer, S.; Gøgsig, T. M.*; Lindhardt, A. T.*; Skrydstrup, T.*
      Chem. Eur. J. 2013 19, 17603–17607.

(6) “Gold-Catalyzed Carbene Transfer to Alkynes: Access to 2,4-Disubstituted Furans”
Kramer, S.; Skrydstrup, T.*
Angew. Chem. Int. Ed. 2012, 51, 4681–4684.

(5) “Cu(I)-Catalyzed Oxidative Cyclization of Alkynyl Oxiranes and Oxetanes”
Gronnier, C.; Kramer, S.; Odabachian, Y.; Gagosz, F.*
J. Am. Chem. Soc. 2012, 134, 828–831.

(4) “Metal-Free Halonium Mediated Acetate Shifts of Ynamides to Access α-Halo Acrylamides/ Acrylimides”
Kramer, S.; Friis, S. D.; Xin, Z.; Odabachian, Y.; Skrydstrup, T.*
Org. Lett. 2011, 13, 1750–1753.

(3) “Taking Advantage of the Ambivalent Reactivity of Ynamides in Gold Catalysis: A Rare Case of Alkyne Dimerization”
Kramer, S.; Odabachian, Y.; Overgaard, J.; Rottländer, M.; Gagosz, F.*; Skrydstrup, T.*
Angew. Chem. Int. Ed. 2011, 50, 5090–5094.

(2) “Access to 2,5-Diamidopyrroles and 2,5-Diamidofurans by Au(I)-Catalyzed Double Hydroamination or Hydration of 1,3-Diynes”
Kramer, S.; Madsen, J. L. H.; Rottländer, M.; Skrydstrup, T.*
Org. Lett. 2010, 12, 2758–2761.

(1) “Highly Regioselective Au(I)-Catalyzed Hydroamination of Ynamides and Propiolic Acid Derivatives with Anilines”
Kramer, S.; Dooleweerdt, K.; Lindhardt, A. T.; Rottländer, M.; Skrydstrup, T.*
Org. Lett. 2009, 11, 4208–4211.