Publications

(45) "Benzylic C(sp3)-H Phosphonylation via Dual Photo and Copper Catalysis"
Li, H.-H.; Liu, Y.; Kramer, S.*
Angew. Chem. Int. Ed. 2025, 64, e202420613.

Among most accessed publications in Angewandte Chemie during November 2024

(44) "Photoinduced Copper-Catalyzed Enantioselective Allylic C(sp3)-H Oxidation of Acyclic 1-Aryl-2-alkyl Alkenes as Limiting Substrates"
Chen, X.; Li, H.-H.; Kramer, S.*
Angew. Chem. Int. Ed. 2024, 63, e202413190.

Among most accessed publications in Angewandte Chemie during August 2024

(43) "Generation of Sulfamoyl Radical For the Modular Synthesis of Sulfonamides"
Lv, H.; Chen, X.; Zhang, X.; Kramer, S.*; Lian, Z.*
ACS Catal. 2024, 14, 6513–6524.

(42) "Photoinduced Transition-Metal-Catalyzed Enantioselective Functionalization of Non-Acidic C(sp3)-H Bonds"
Chen, X.; Kramer, S.*
Chem Catal. 2024, 4, 100854.

(41) "Recent Developments for Intermolecular Enantioselective Amination of Non-Acidic C(sp3)–H Bonds"
Li, H.-H.; Chen, X.; Kramer, S.*
Chem. Sci. 2023, 14, 13278–13289.

Selected as "2023 most popular catalysis articles in Chemical Science"

(40) "Mechanochemical Synthesis of Aryl Fluorides by Using Ball Milling and a Piezoelectric Material as the Redox Catalyst"
Wang, X.; Zhang, X.; Xue, L.; Wang, Q.; You, F.; Dai, L.; Wu, J.; Kramer, S.*; Lian, Z.*
Angew. Chem. Int. Ed. 2023, 62, e202307054.

(39) "Enantioselective Intermolecular Radical Amidation and Amination of Benzylic C-H Bonds via Dual Copper and Photocatalysis"
Chen, X.; Lian Z.*, Kramer, S.*
Angew. Chem. Int. Ed. 2023, 62, e202217638.

Most accessed publication in Angewandte Chemie during February 2023
Highlighted by T. West in Nature Synthesis
Highlighted in Org. Process Res. Dev.
Highlighted by M. Oestreich et al. in Synfacts

(38) "Carbonylative Cross-Electrophile Coupling between Aryl Bromides and Aryl Triflates Enabled by Palladium and Rhodium Cooperative Catalysis and CO as Reductant"
Chen, G.; Zhou, R.; Zhang, X.; Xiao, X.; Kramer, S.*; Cheng, G.-J.*; Lian, Z.*
ACS Catal. 2022, 12, 14582–14591.

(37) "Photo-induced metal-free dehydrogenative N-N homo-coupling"
Balakrishna, B.; Mossin, S.; Kramer, S.*
Chem. Commun. 2022, 58, 10977–10980.

(36) "Enantioselective Four-Component Arylsulfonylcyanation of Vinylarenes via the Insertion of SO2 enabled by SOgen as SO2 Surrogate"
Chen, L.; Zhang, X.; Zhou, M.; Shen, L.; Kramer, S.*, Lian, Z.*
ACS Catal. 2022, 12, 10764–10770.

(35) "Redox-Neutral Ni-Catalyzed sp3 C–H Alkylation of alpha-Olefins with Unactivated Alkyl Bromides"
Buendia, M. B.; Higginson, B.; Kegnæs, S.; Kramer, S.*, Martin, R.*
ACS Catal. 2022, 12, 3815–3820.

(34) “Copper-Catalyzed Alkynylation of Benzylic C–H Bonds with Alkynylboronic Esters”
Buendia, M. B.; Balin, J.-G. J.; Andersen, M. E.; Lian, Z.; Kramer, S.*
Synlett 2022, 33, 150–154.
- Invited contribution in connection with nomination for EuChemS Young Investigator Award

(33) "Design and Applications of a SO2 Surrogate in Palladium-Catalyzed Direct Aminosulfonylation between Aryl Iodides and Amines"
Jia, X.; Kramer, S.; Skrydstrup, T.; Lian, Z.*
Angew. Chem. Int. Ed. 2021, 60, 7353–7359.
- Hot paper

(32) “Heterogeneous Formic Acid Production by Hydrogenation of CO Catalyzed by Ir-bpy Embedded in Polyphenylene Porous Organic
Polymers“
Bennedsen, N. R.; Christensen, D. B.; Mortensen, R. L.; Wang, B.; Kramer, S.*; Kegnæs, S.*
ChemCatChem 2021, 13, 1781–1786.

(31) “Nickel-Catalyzed Cross-Electrophile Coupling Reaction for the Synthesis of gem-Difluorovinyl Arenes”
Xiong, B.; Wang, T.; Sun, H.; Li, Y.; Kramer, S.*; Cheng, G.-J.*; Lian, Z.*
ACS Catal. 2020, 10, 13616–13623.

(30) “A Nickel-Bisdiamine Porous Organic Polymer as Heterogeneous Chiral Catalyst for Asymmetric Michael Addition to Aliphatic Nitroalkenes”
Buendia, M. B.; Kegnæs, S.*; Kramer, S.*
Adv. Synth. Catal. 2020, 362, 5506–5512.

(29) “Dual Nickel/Palladium-Catalyzed Reductive Cross-Coupling Reactions Between Two Phenol Derivatives”
Xiong, B.; Li, Y.; Wei, Y.; Kramer, S.*; Lian, Z.*
Org. Lett. 2020, 22, 6334–6338.

(28) “A Chiral Porous Organic Polymer as Heterogeneous Ligand for Enantioselective Pd-Catalyzed C(sp3)–H Functionalization”
Bennedsen, N. R.; Kramer, S.*; Kegnæs, S.*
Catal. Sci. Technol. 2020, 10, 7697–7705.

(27) “Silylcarboxylic Acid as Bifunctional Reagents: Application in Palladium-Catalyzed External-CO-Free Carbonylative Cross-Coupling Reactions”
Li, X.; Xu, J.; Zhang, X.; Kramer, S.; Skrydstrup, T.; Lian Z.*
Adv. Synth. Catal. 2020, 362, 4078–4083.

(26) “Homogeneous Gold-Catalyzed Aryl-Aryl Coupling Reactions”
Kramer, S.*
Synthesis 2020, 52, 2017–2030.
- Invited contribution

(25) "Nickel-Catalyzed Intramolecular Desulfitative C-N Coupling: A Synthesis of Aromatic Amines"
Liu, J.; Jia, X.; Chen, X.; Sun, H.; Li, Y.; Kramer, S.; Lian, Z.*
J. Org. Chem. 2020, 85, 5702–5711.

(24) "Study of CoCu Alloy Nanoparticles Supported on MOF-Derived Carbon for Hydrosilylation of Ketones"
Christensen, D. B.; Mortensen, R. L.; Kramer, S.; Kegnæs, S.*
Catal. Lett. 2020, 150, 1537–1545.

(23) “Enantioselective Aryl-Aryl Coupling Facilitated by Chiral Binuclear Gold Complexes”
Himmelstrup, J.; Buendia, M. B.; Sun, X.-W.; Kramer, S.*
Chem. Commun. 2019, 55, 12988–12991.

(22) “Palladium on Carbon-Catalyzed α-Alkylation of Ketones with Alcohols as Electrophiles: Scope and Mechanism”
Bennedsen, N. R.; Mortensen, R. M.; Kramer, S.*; Kegnæs, S.*
J. Catal. 2019, 371, 153–160.

(21) "Synthesis of α-Substituted Primary Benzylamines through Copper-Catalyzed Cross-Dehydrogenative Coupling”
Kramer, S.*
Org. Lett. 2019, 21, 65–69.

(20) "Asymmetric Synthesis of Chiral Spiroketal Bisphosphine Ligands and Their Application in Enantioselective Olefin Hydrogenation"
        Huang, J.; Hong, M.; Wang, C.-C.; Kramer, S.*; Lin, G.-Q.; Sun, X.-W.*
        J. Org. Chem. 2018, 83, 12838–12846.
   (Highlighted in SYNFACTS 2018, 14, 1282)

(19) "Porous Organic Polymers Containing Active Mononuclear Metal Centers as Catalysts for Synthetic Organic Chemistry"
Kramer, S.*; Bennedsen, N. R.; Kegnæs, S.*
ACS Catal. 2018, 8, 6961–6982.

(18) "Asymmetric Organocatalytic [4 + 1] Annulations: Enantioselective Construction of Multifunctionalized Spirocyclopentane Oxindoles
        Bearing α,α-Disubstituted α-Amino-β-keto Esters"
        Wang, C.-C.; Huang, J.; Li, X.-H.; Kramer, S.; Lin, G.-Q.; Sun, X.-W.*
        Org. Lett. 2018, 20, 2888–2891.

(17) “Silylative Pinacol Coupling Catalyzed by Nitrogen-Doped Carbon-Encapsulated Nickel/Cobalt Nanoparticles: Evidence for a Silyl Radical
       Pathway”
       Kramer, S.; Hejjo, F.; Rasmussen, K. H.; Kegnæs, S.*
       ACS Catal. 2018, 8, 754–759.

(16) "Cobalt-Nickel Alloy Catalysts for Hydrosilylation of Ketones Synthesized by Utilizing Metal-Organic Framework as Template"
Bennedsen, N. R.; Kramer, S.; Mielby, J. J.; Kegnæs, S.*
Catal. Sci. Technol. 2018, 8, 2434–2440.

(15) “Asymmetric Total Syntheses of (−)-α-Lycorane, (−)-Zephyranthine and Formal Synthesis of (+)-Clivonine”
Chen, Y.-J.; Cai, S.-L.; Wang, C.-C.; Cheng, J.-D.; Kramer, S.; Sun, X.-W.*
Chem. Asian J. 2017, 12, 1309–1313.

(14) “Evidence for Single Electron Pathways in the Reaction Between Palladium(II) Dialkyl Complexes and Alkyl Bromides under Thermal and
       Photo-Induced Conditions”
       Andersen, T. L.; Kramer, S.*; Overgaard, J.; Skrydstrup, T.*
       Organometallics 2017, 36, 2058–2066.

(13) “Nitrogen-Doped Carbon Encapsulated Nickel/Cobalt Nanoparticle Catalysts for Olefin Migration of Allylarenes”
Kramer, S.; Mielby, J. J.; Buss, K. S.; Kasama, T.; Kegnæs, S.*
ChemCatChem 2017, 9, 2930–2934.

(12) “Recent Advances in Gold-Catalyzed Intermolecular Aryl C–H Functionalization”
Kramer, S.*
Chem. Eur. J. 2016, 22, 15584–15598.

(11) “Use of a New Spirophosphine to Achieve Catalytic Enantioselective [4+1] Annulations of Amines with Allenes to Generate
      Dihydropyrroles”
       Kramer, S.; Fu, G. C.*
       J. Am. Chem. Soc. 2015, 137, 3803–3806.

(10) “Access to Dihydroisoquinolines via Gold-Catalyzed Formal [4+2] Cycloaddition”
Xin, Z.; Kramer, S.*; Overgaard, J.; Skrydstrup, T.*
Chem. Eur. J. 2014, 20, 7926–7930.

(9) Kramer, S.; Gagosz, F.
“From Gold in Nature to Gold Catalysts” in Gold Catalysis – An Homogeneous Approach
Toste, F. D.; Michelet, V., Eds.; Imperial College Press, 2014; pp 1–49.

(8) “Divergent Product Selectivity in Gold- versus Silver-Catalyzed Reaction of 2-Propynyloxy-6-Fluoropyridines with Arylamines”
Gronnier, C.; Bel, P. F. D.; Henrion, G.; Kramer, S.; Gagosz, F.*
Org. Lett. 2014, 16, 2092–2095.

(7) “Generation of Stoichiometric Ethylene and Isotopic Derivatives and Application in Transition Metal-Catalyzed Vinylation and Enyne
      Metathesis”
      Min, G. K.; Bjerglund, K.; Kramer, S.; Gøgsig, T. M.*; Lindhardt, A. T.*; Skrydstrup, T.*
      Chem. Eur. J. 2013 19, 17603–17607.

(6) “Gold-Catalyzed Carbene Transfer to Alkynes: Access to 2,4-Disubstituted Furans”
Kramer, S.; Skrydstrup, T.*
Angew. Chem. Int. Ed. 2012, 51, 4681–4684.

(5) “Cu(I)-Catalyzed Oxidative Cyclization of Alkynyl Oxiranes and Oxetanes”
Gronnier, C.; Kramer, S.; Odabachian, Y.; Gagosz, F.*
J. Am. Chem. Soc. 2012, 134, 828–831.

(4) “Metal-Free Halonium Mediated Acetate Shifts of Ynamides to Access α-Halo Acrylamides/ Acrylimides”
Kramer, S.; Friis, S. D.; Xin, Z.; Odabachian, Y.; Skrydstrup, T.*
Org. Lett. 2011, 13, 1750–1753.

(3) “Taking Advantage of the Ambivalent Reactivity of Ynamides in Gold Catalysis: A Rare Case of Alkyne Dimerization”
Kramer, S.; Odabachian, Y.; Overgaard, J.; Rottländer, M.; Gagosz, F.*; Skrydstrup, T.*
Angew. Chem. Int. Ed. 2011, 50, 5090–5094.

(2) “Access to 2,5-Diamidopyrroles and 2,5-Diamidofurans by Au(I)-Catalyzed Double Hydroamination or Hydration of 1,3-Diynes”
Kramer, S.; Madsen, J. L. H.; Rottländer, M.; Skrydstrup, T.*
Org. Lett. 2010, 12, 2758–2761.

(1) “Highly Regioselective Au(I)-Catalyzed Hydroamination of Ynamides and Propiolic Acid Derivatives with Anilines”
Kramer, S.; Dooleweerdt, K.; Lindhardt, A. T.; Rottländer, M.; Skrydstrup, T.*
Org. Lett. 2009, 11, 4208–4211.